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A453, PH & duplex bolting · ASTM A1082 bolting · ASTM A276 / A479 bar · ASTM A182 F51 / F60

Duplex 2205 Stainless (UNS S31803 / S32205)

Twice the yield strength of 316 with far better chloride stress-corrosion resistance — the standard duplex for offshore, seawater and sour-service bolting.

UNS S31803 · S32205Alloy 2205 duplex (22 Cr – 5 Ni – 3 Mo – N)Type Ferritic-austenitic duplex stainless steel, solution annealed and water quenched
Material overview

What Duplex 2205 is.

Duplex 2205 is a 22 percent chromium, 5 percent nickel, 3 percent molybdenum stainless steel with a nitrogen addition, balanced to solidify as roughly half ferrite and half austenite. The mixed structure gives it a 65 ksi minimum yield, about double that of 316, together with resistance to chloride pitting and stress-corrosion cracking that austenitic grades cannot match.

S32205 is the tighter-chemistry version of S31803 with higher nitrogen and molybdenum minimums; most modern bar is dual certified. ASTM A1082 governs 2205 bolting. We machine studs, bolts and nuts from certified solution-annealed bar and supply them to A1082 with heat traceability.

Get a QuoteDownload the Duplex 2205 data sheet (PDF)
Tensile90 ksi min (S31803) · 95 ksi (S32205)
Yield65 ksi min
Hardness30 HRC / 290 HBW max
Solution anneal1900 °F, water quench
PREN≈ 35
MagneticYes (about half ferrite)
Nominal composition
Fe balance ≈ 67.0%Cr ≈ 22.50%Ni ≈ 5.50%Mo ≈ 3.25%Mn ≈ 1.00%Si ≈ 0.50%C, P, S, N trace

Midpoints of the specification ranges, for orientation only. Limits are in the table below.

Specifications & technical data

Chemical composition.

Download the data sheet (PDF) →
Chemical composition — S32205 (2205) per ASTM A1082 Table 1
ElementSymbolMin %Max %
CarbonC—0.030
ManganeseMn—2.00
PhosphorusP—0.030
SulfurS—0.020
SiliconSi—1.00
ChromiumCr22.023.0
NickelNi4.56.5
MolybdenumMo3.03.5
NitrogenN0.140.20

Values per ASTM A1082/A1082M-16(2021) Tables 1 and 4 (verified against the specification). Confirm the edition called out on your purchase order with our estimating team.

Physical properties (typical)
Density0.283 lb/in³ (7.80 g/cm³)
Modulus of elasticity27.6 × 10⁶ psi (190 GPa)
Thermal expansion (68–212 °F)7.2 µin/in·°F
MagneticYes
Specifications & technical data

Mechanical properties.

Mechanical properties — 2205 duplex bolting per ASTM A1082 Table 4
UNSTensile strength, min (ksi)Yield strength, min (ksi)Elongation, min (%)Hardness, max
S3180390652530 HRC / 290 HBW
S3220595652530 HRC / 290 HBW

Values per ASTM A1082/A1082M-16(2021) Tables 1 and 4 (verified against the specification). Confirm the edition called out on your purchase order with our estimating team. Solution annealed at 1900 ± 25 °F and water quenched.

Chemical composition — S31803 per ASTM A1082 Table 1
ElementSymbolMin %Max %
CarbonC—0.030
ManganeseMn—2.00
PhosphorusP—0.030
SulfurS—0.020
SiliconSi—1.00
ChromiumCr21.023.0
NickelNi4.56.5
MolybdenumMo2.53.5
NitrogenN0.080.20

Values per ASTM A1082/A1082M-16(2021) Tables 1 and 4 (verified against the specification). Confirm the edition called out on your purchase order with our estimating team.

Heat treatmentSolution annealed at 1900 ± 25 °F (1040 °C) and water quenched. Duplex grades are not hardened by heat treatment; they must not be held between 700 and 1800 °F, where sigma and other intermetallic phases form.
Standards

Specifications that apply.

ASTM A1082 / A1082MHigh strength precipitation hardening and duplex stainless steel bolting
ASTM A276 / A4792205 bar stock
ASTM A182 Grades F51 / F60Forged duplex flanges and fittings the bolting is matched to
NACE MR0175 / ISO 15156Duplex stainless steels for sour service within their limits
NORSOK M-630 / MDS D45Common offshore duplex bolting requirement
Forms we supply

How Duplex 2205 ships from Houston.

  • Full-thread studs and stud bolts
  • Hex and heavy hex bolts
  • Socket head cap screws
  • Hex nuts in the same alloy
  • Threaded rod
  • Machined components from certified bar
Companion grades
45 products in this grade

Duplex 2205 fasteners we make.

All products →

Every item is manufactured to your drawing or standard in Duplex 2205, imperial or metric, with an EN 10204 3.1 certificate.

Where Duplex 2205 is used
Offshore platform and subsea flange boltingSeawater cooling, firewater and desalination systemsSour gas and produced-water serviceChemical process piping in chloridesPulp and paper digesters and bleach plantsHeat exchangers and pressure vessels in 2205
The buyer’s guide

What is duplex 2205?

Duplex stainless steels combine ferrite and austenite in roughly equal amounts. The ferrite phase brings strength and resistance to chloride stress-corrosion cracking; the austenite brings toughness and general corrosion resistance. 2205 is the general-purpose duplex: with a pitting resistance equivalent number of about 35 it outperforms 316 in seawater and brines, and its 65 ksi yield lets designers use smaller fasteners or higher loads. Toughness is good down to about −50 °F, below which the ferrite becomes brittle.

S31803 or S32205?

S32205 is a narrower chemistry inside the S31803 range, with chromium at 22 percent minimum, molybdenum at 3.0 percent and nitrogen at 0.14 percent. Those minimums guarantee the corrosion resistance the alloy is bought for; S31803 material at the bottom of its ranges can fall short. A1082 sets a 95 ksi tensile for S32205 against 90 for S31803. Specify S32205 unless a legacy document calls for S31803.

Handling and heat treatment limits

Duplex bolting is supplied solution annealed and must stay that way. Any hot work, welding or stress relief between about 700 and 1800 °F risks sigma-phase precipitation, which destroys toughness and corrosion resistance. We machine from annealed bar and do not heat treat after threading. Keep service temperature below 570 °F.

Testing, certification and marking

  • Tensile and hardness tested per lot on the finished product
  • Grade or alloy marking 32205 or 31803 (A1082 Table 5) and manufacturer's identification on every piece
  • EN 10204 3.1 material test report with heat number and chemistry; 3.2 witness available

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